Surface Transitions for Confined Associating Mixtures

Details Surface Transitions for Confined Associating Mixtures Surface Transitions for Confined Associating Mixtures

1997-09-29

arxiv.org/abs/cond-mat/9709321v1

Physics

Condensed Matter

Soft Condensed Matter

LaTeX document, documentstyle[aps,preprint]{revtex}, psfig.sty, bibtex, 13 pages, 4 figures

Scientific paper

10.1103/PhysRevLett.80.1252

Thin films of binary mixtures that interact through isotropic forces and directionally specific "hydrogen bonding" are considered through Monte Carlo simulations. We show, in good agreement with experiment, that the single phase of these mixtures can be stabilized or destabilized on confinement. These results resolve a long standing controversy, since previous theories suggest that confinement only stabilizes the single phase of fluid mixtures.

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