Surface-to-volume ratio with oscillating gradients

Details Surface-to-volume ratio with oscillating gradients Surface-to-volume ratio with oscillating gradients

2011-01-13

arxiv.org/abs/1101.2669v2

J. Magn. Reson. (2011)

Physics

Condensed Matter

Soft Condensed Matter

6 pages, 1 figure

Scientific paper

10.1016/j.jmr.2011.02.011

Restrictions to diffusion result in the dispersion of the bulk diffusion coefficient. We derive the exact universal high-frequency behavior of the diffusion coefficient in terms of the surface-to-volume ratio of the restrictions. This frequency dependence can be applied to quantify structure of complex samples with NMR using oscillating field gradients and static-gradient CPMG. We also demonstrate the inter-relations between different equivalent diffusion metrics, and describe how to calculate the effect of restrictions for arbitrary gradient waveforms.

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