Physics – Condensed Matter – Superconductivity
Scientific paper
2009-09-16
Supercond. Sci. Technol. 23 (2010) 045001
Physics
Condensed Matter
Superconductivity
This paper has been withdrawn because new version of the paper has been submitted as arXiv:0912.1840
Scientific paper
10.1088/0953-2048/23/4/045001
We have discovered a new iron pnictide oxide superconductor (Fe2As2)(Sr4(Mg,Ti)2O6). This material is isostructual with (Fe2As2)(Sr4M2O6) (M = Sc, Cr), which was found in our previous study. The structure of this compound is tetragonal with a space group of P4/nmm and consists of the anti-fluorite type FeAs and perovskite-type blocking layers. The lattice constants are a = 3.935 A and c = 15.952 A for (Fe2As2)(Sr4MgTiO6). In both magnetization and resistivity measurements, this compound exhibits superconductivity below 10 K. Moreover, ratio of Mg and Ti in this compound can be changed toward Ti-rich composition. (Fe2As2)(Sr4Mg1-xTi1+xO6) phase is obtained at 0 < x as a main phase, and Tc and superconducting volume fraction increase with increasing x. The highest Tc(onset) was confirmed at 39 K for x = 0.6 in resistivity measurement.
Katsura Yukari
Kawaguchi Naoto
Kishio Kohji
Ogino Hiraku
Sato Shinya
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