Physics – Condensed Matter
Scientific paper
1995-03-22
Physics
Condensed Matter
13 pages, REVTEX, 10 ps figures available by e-mail.
Scientific paper
10.1103/PhysRevB.52.9330
Theoretical models for the liquid-vapor and metal-nonmetal transitions of alkali fluids are investigated. Mean-field models are considered first but shown to be inadequate. An alternate approach is then studied in which each statistical configuration of the material is treated as inhomogeneous, with the energy of each ion being determined by its local environment. Nonadditive interactions, due to valence electron delocalization, are a crucial feature of the model. This alternate approach is implemented within a lattice-gas approximation which takes into account the observed mode of expansion in the materials of interest and which is able to treat the equilibrium density fluctuations. We have carried out grand canonical Monte Carlo simulations, for this model, which allow a unified, self-consistent, study of the structural, thermodynamic, and electronic properties of alkali fluids. Applications to Cs, Rb, K, and Na yield results in good agreement with observations.
Chacon Elizabeth
Hernandez John P.
Tarazona Pedro
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