Structure of ternary additive hard-sphere fluid mixtures

Details Structure of ternary additive hard-sphere fluid mixtures Structure of ternary additive hard-sphere fluid mixtures

2002-05-27

arxiv.org/abs/cond-mat/0205552v2

Phys. Rev. E 66, 061203 (2002)

Physics

Condensed Matter

Statistical Mechanics

11 pages, including 8 figures; A minor change; accepted for publication in PRE

Scientific paper

10.1103/PhysRevE.66.061203

Monte Carlo simulations on the structural properties of ternary fluid mixtures of additive hard spheres are reported. The results are compared with those obtained from a recent analytical approximation [S. B. Yuste, A. Santos, and M. Lopez de Haro, J. Chem. Phys. 108, 3683 (1998)] to the radial distribution functions of hard-sphere mixtures and with the results derived from the solution of the Ornstein-Zernike integral equation with both the Martynov-Sarkisov and the Percus-Yevick closures. Very good agreement between the results of the first two approaches and simulation is observed, with a noticeable improvement over the Percus-Yevick predictions especially near contact.

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