Physics – Condensed Matter – Statistical Mechanics
Scientific paper
Aug 1987
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987apj...319..195d&link_type=abstract
Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 319, Aug. 1, 1987, p. 195-206.
Physics
Condensed Matter
Statistical Mechanics
85
Coulomb Collisions, Partitions (Mathematics), Polarization Characteristics, Statistical Mechanics, Stellar Winds, Visible Spectrum, Atomic Interactions, Functions (Mathematics), Plasma Chemistry
Scientific paper
We discuss a recent controversy about the Planck-Larkin partition function, and present optical simulations of high-quality spectra from laboratory hydrogen plasmas (Wiese, Kelleher, and Paquette) using several partition function formalisms. We point out that the controversy has arisen from a misunderstanding about the use of the Planck-Larkin partition function. A Planck-Larkin cancellation may still have its place in equations of state that are based on quantum-statistical many-body theory (i.e., the "physical picture"). However, experimental evidence shows that it is inconsistent to use the Planck-Larkin partition function as the internal partition function in simple models of reacting gases (i.e., the "chemical picture"). Moreover, the more sophisticated equations of state of the physical picture will have to be subjected to the same comparison with experimental data. We also address the question of plasma polarization shifts of bound-state energies. We discuss the static-screened Coulomb potential (SSCP) as an atomic potential: from theoretical considerations and observational constraints we conclude that it should not be used. The only useful result of the SSCP potential its prediction of the number of excited be obtained by alternative means, e.g., by an occupation probability formalism.
Anderson Lawrence
Dappen Werner
Mihalas Dimitri
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