Physics – Condensed Matter – Materials Science
Scientific paper
2004-07-26
Physics
Condensed Matter
Materials Science
4 pages, 3 figures
Scientific paper
10.1063/1.2014937
Ion assisted deposition (IAD) has been investigated for the growth of GaN, and the resulting films studied by x-ray diffraction and absorption spectroscopy and by transmission electron microscopy. IAD grown stoichiometric GaN consists of random-stacked quasicrystals of some 3 nm diameter. Amorphous material is formed only by incorporation of 15% or more oxygen, which we attribute to the presence of non-tetrahedral bonds centered on oxygen. The ionic favourability of heteropolar bonds and its strikingly simple constraint to even-membered rings is the likely cause of the instability of stoichiometric a-GaN.
Ariza M. J.
Bittar A.
Bonnet B.
Budde F.
Granville Simon
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