Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2011-01-28
Physics
Condensed Matter
Strongly Correlated Electrons
accepted for publication in PRB as a rapid communication
Scientific paper
A dense phase of a post-layered perovskite Sr3Co2O6 was created by a high-pressure and high-temperature synthetic route and quenched to ambient conditions. The structure of Sr3Co2O6 was determined by synchrotron X-ray powder diffraction. Sr3Co2O6 crystallizes in the K4CdCl6-type structure (an infinite chain-type structure), which is 6% denser than the known, iso-compositional layered perovskite Sr3Co2O7-d (d~1). The K4CdCl6-type Sr3Co2O6 shows complex magnetic behavior reflecting the spin-chain nature as well as the analogue oxides Ca3Co2O6 and Ca3CoRhO6, whose microscopic magnetic origin is still highly debated.
Guo Y. F.
Katsuya Y.
Kobayashi Koji
Li Jiying
Matsushita Yasuhiro
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