Solvent Driven Formation of Bolaamphiphilic Vesicles

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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J. Phys. Chem. B, accepted

Scientific paper

10.1021/jp0558021

We show that a spontaneous bending of single layer bolaamphiphiles results from the frustration due to the competition between core-core and tail-solvent interactions. We find that spherical vesicles are stable under rather general assumptions on these interactions described within the Flory-Huggins theory. We consider also the deformation of the vesicles in an external magnetic field that has been recently experimentally observed.

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