Single Polymer Confinement in a Slit: Correlation between structure and dynamics

Details Single Polymer Confinement in a Slit: Correlation between structure and dynamics Single Polymer Confinement in a Slit: Correlation between structure and dynamics

2007-02-06

arxiv.org/abs/cond-mat/0702152v4

Physics

Condensed Matter

Soft Condensed Matter

10 pages, 16 figures

Scientific paper

In this paper, we construct an effective model for the dynamics of an excluded-volume chain under confinement, by extending the formalism of Rouse modes. We make specific predictions about the behavior of the modes for a single polymer confined to a slit. The results are tested against Monte Carlo simulations using the bond-fluctuation algorithm which uses a lattice representation of the polymer chain with excluded-volume effects.

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