Single-order-parameter description of glass-forming liquids: A one-frequency test

Details Single-order-parameter description of glass-forming liquids: A one-frequency test Single-order-parameter description of glass-forming liquids: A one-frequency test

2006-10-30

arxiv.org/abs/cond-mat/0610852v4

J. Chem. Phys. 126, 074502 (2007)

Physics

Condensed Matter

Soft Condensed Matter

Replaces arXiv:cond-mat/0405709

Scientific paper

10.1063/1.2434963

Thermo-viscoelastic linear-response functions are calculated from the master equation describing viscous liquid inherent dynamics. From the imaginary parts of the frequency-dependent isobaric specific heat, isothermal compressibility, and isobaric thermal expansion coefficient, we define a "linear dynamic Prigogine-Defay ratio" with the property that if this quantity is unity atone frequency, then it is unity at all frequencies. This happens if and only if there is a single-order-parameter description of the thermo-viscoelastic linear responses via an order parameter (which may be non-exponential in time). Generalizations to other cases of thermodynamic control parameters than temperature and pressure are treated in an Appendix.

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