Single Crystal Study of Competing Rhombohedral and Monoclinic Order in Lead Zirconate Titanate

Details Single Crystal Study of Competing Rhombohedral and Monoclinic Order in Lead Zirconate Titanate Single Crystal Study of Competing Rhombohedral and Monoclinic Order in Lead Zirconate Titanate

2010-11-15

arxiv.org/abs/1011.3509v1

Phys. Rev. Lett. 105, 207601 (2010)

Physics

Condensed Matter

Materials Science

Scientific paper

10.1103/PhysRevLett.105.207601

Neutron diffraction data obtained on single crystals of PbZr1-xTixO3 with x = 0.325 and x = 0.460, which lie on the pseudorhombohedral side of the morphotropic phase boundary, suggest a coexistence of rhombohedral (R3m/R3c) and monoclinic (Cm) domains and that monoclinic order is enhanced by Ti substitution. A monoclinic phase with a doubled unit cell (Cc) is ruled out as the ground state.

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