Simple model for the phase coexistence and electrical conductivity of alkali fluids

Details Simple model for the phase coexistence and electrical conductivity of alkali fluids Simple model for the phase coexistence and electrical conductivity of alkali fluids

1994-03-17

arxiv.org/abs/cond-mat/9403067v1

Physics

Condensed Matter

RevTex, 11 pages, 2 ps figure files appended, submitted to PRL

Scientific paper

10.1103/PhysRevLett.74.142

We report the first theoretical model for the alkali fluids which yields a liquid-vapor phase coexistence with the experimentally observed features and electrical conductivity estimates which are also in accord with observations. We have carried out a Monte Carlo simulation for a lattice gas model which allows an integrated study of the structural, thermodynamic, and electronic properties of metal-atom fluids. Although such a technique is applicable to both metallic and nonmetallic fluids, non-additive interactions due to valence electron delocalization are a crucial feature of the present model.

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