Simple derivation of the frequency dependent complex heat capacity

Details Simple derivation of the frequency dependent complex heat capacity Simple derivation of the frequency dependent complex heat capacity

2007-06-27

arxiv.org/abs/0706.4047v1

Thermochimica Acta 460 (25/08/2007) 85-87

Physics

Condensed Matter

Other Condensed Matter

Scientific paper

10.1016/j.tca.2007.05.010

This paper gives a simple derivation of the well-known expression of the frequency dependent complex heat capacity in modulated temperature experiments. It aims at clarified again that the generalized calorimetric susceptibility is only due to the non-equilibrium behaviour occurring in the vicinity of thermodynamic equilibrium of slow internal degrees of freedom of a sample when the temperature oscillates at a well determined frequency.

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