Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2008-01-22
Physics
Condensed Matter
Soft Condensed Matter
10 pages, 2 figures
Scientific paper
A lattice model is used to estimate the self-diffusivity of entangled cyclic and linear polymers in blends of varying compositions. To interpret simulation results, we suggest a minimal model based on the physical idea that constraints imposed on a cyclic polymer by infiltrating linear chains have to be released, before it can diffuse beyond a radius of gyration. Both, the simulation, and recently reported experimental data on entangled DNA solutions support the simple model over a wide range of blend compositions, concentrations, and molecular weights.
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