Self-contained Kondo effect in single molecules

Details Self-contained Kondo effect in single molecules Self-contained Kondo effect in single molecules

2006-01-05

arxiv.org/abs/cond-mat/0601084v1

PRL 95, 267202 (2005)

Physics

Condensed Matter

Strongly Correlated Electrons

4 pages, 5 figures (eps)

Scientific paper

10.1103/PhysRevLett.95.267202

Kondo coupling of f and conduction electrons is a common feature of f-electron intermetallics. Similar effects should occur in carbon ring systems(metallocenes). Evidence for Kondo coupling in Ce(C8H8)2 (cerocene) and the ytterbocene Cp*2Yb(bipy) is reported from magnetic susceptibility and L_III-edge x-ray absorption spectroscopy. These well-defined systems provide a new way to study the Kondo effect on the nanoscale, should generate insight into the Anderson Lattice problem, and indicate the importance of this often-ignored contribution to bonding in organometallics.

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