Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection

Details Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection

2007-11-27

arxiv.org/abs/0711.4157v1

Physics

Condensed Matter

Materials Science

3 pages, 5 figures; Journal of the American Chemical Society, in press, 2007

Scientific paper

Single-walled carbon nanotubes (SWNTs) are potential materials for future nanoelectronics. Since the electronic and optical properties of SWNTs strongly depend on tube diameter and chirality, obtaining SWNTs with narrow (n,m) chirality distribution by selective growth or chemical separation has been an active area of research. Here, we demonstrate that a new, bimetallic FeRu catalyst affords SWNT growth with narrow diameter and chirality distribution in methane CVD. At 600C, methane CVD on FeRu catalyst produced predominantly (6,5) SWNTs according to Uv-vis-NIR absorption and photoluminescence excitation/emission (PLE) spectroscopic characterization. At 850C, the dominant semiconducting species produced are (8,4), (7,6) and (7,5) SWNTs, with much narrower distributions in diameter and chirality than materials grown by other catalysts. Further, we show that narrow-diameter/chirality growth combined with chemical separation by ion exchange chromatography (IEC) greatly facilitate achieving single-(m,n) SWNT samples, as demonstrated by obtaining highly enriched (8,4) SWNTs with near elimination of metallic SWNTs existing in the as-grown material.

Affiliated with

Also associated with

No associations

Rating

Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-685583