Robust paramagnetism in Bi2-xMxRu2O7 (M=Mn,Fe,Co,Ni,Cu) pyrochlore

Details Robust paramagnetism in Bi2-xMxRu2O7 (M=Mn,Fe,Co,Ni,Cu) pyrochlore Robust paramagnetism in Bi2-xMxRu2O7 (M=Mn,Fe,Co,Ni,Cu) pyrochlore

2002-05-24

arxiv.org/abs/cond-mat/0205519v1

Physics

Condensed Matter

Superconductivity

submitted, Phys. Rev. B

Scientific paper

10.1103/PhysRevB.66.094429

We report physical property characterization of Bi2-xMxRu2O7 pyrochlores, including magnetic suseptibility, resistivity, and Seebeck coefficients. The solid solution exists up to x=0.5 for (M=Cu,Ni,Co) and up to x=0.1 for (M=Fe,Mn). None of the doped materials exhibit ferromagnetism or any localized ruthenium moment behavior. Instead we find the Ru-O and Bi-O sublattices to be essentially independent, with any magnetism resulting from the unpaired transition metal dopant spins. Cobalt substitution for bismuth results in localized Co{2+}, and low temperature spin-glass transitions in several cases. Nickel moments on the pyrochlore lattice display properties intermediate to localized and itinerant. Finally, copper doping results in only an enhancement of the Pauli metallic density of states.

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