Resonance Anomalous Surface X-ray Scattering

Details Resonance Anomalous Surface X-ray Scattering Resonance Anomalous Surface X-ray Scattering

2005-10-10

arxiv.org/abs/cond-mat/0510235v1

Physics

Condensed Matter

Materials Science

10 pages. To be published in Rad. Phys. Chem as a part of proceedings to X05, Melbourne, Australia, July, 2005

Scientific paper

10.1016/j.radphyschem.2005.07.03

Resonance anomalous surface x-ray scattering (RASXS) technique was applied to electrochemical interface studies. It was used to determine the chemical states of electrochemically formed anodic oxide monolayers on platinum surface. It is shown that RASXS exhibits strong polarization dependence when the surface is significantly modified. The polarization dependence is demonstrated for three examples; anodic oxide formation, sulfate adsorption, and CO adsorption on platinum surfaces. s- and p- polarization RASXS data were simulated with the latest version of ab initio multiple scattering calculations (FEFF8.2). Elementary theoretical considerations are also presented for the origin of the polarization dependence in RASXS.

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