Raman spectra of MgB2 at high pressure and topological electronic transition

Details Raman spectra of MgB2 at high pressure and topological electronic transition Raman spectra of MgB2 at high pressure and topological electronic transition

2001-10-24

arxiv.org/abs/cond-mat/0110511v1

Physics

Condensed Matter

Materials Science

2 figures

Scientific paper

10.1134/1.1490010

Raman spectra of the MgB2 ceramic samples were measured as a function of pressure up to 32 GPa at room temperature. The spectrum at normal conditions contains a very broad peak at ~590 cm-1 related to the E2g phonon mode. The frequency of this mode exhibits a strong linear dependence in the pressure region from 5 to 18 GPa, whereas beyond this region the slope of the pressure-induced frequency shift is reduced by about a factor of two. The pressure dependence of the phonon mode up to ~ 5GPa exhibits a change in the slope as well as a "hysteresis" effect in the frequency vs. pressure behavior. These singularities in the E2g mode behavior under pressure support the suggestion that MgB2 may undergo a pressure-induced topological electronic transition.

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