Quantum Potential for Diffraction and Exchange Effects

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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to appear in the International Journal of Quantum Chemistry

Scientific paper

Semi-classical methods of statistical mechanics can incorporate essential quantum effects by using effective quantum potentials. An ideal Fermi gas interacting with an impurity is represented by a classical fluid with effective electron-electron and electron-impurity quantum potentials. The electron-impurity quantum potential is evaluated at weak coupling, leading to a generalization of the Kelbg potential to include both diffraction and degeneracy effects. The electron-electron quantum potential for exchange effects only is the same as that discussed earlier by others.

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