Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures

Details Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures

2011-06-25

arxiv.org/abs/1106.5142v1

Condens. Matter Phys., 2011, vol. 14, No. 2, 23705:1-12

Physics

Condensed Matter

Mesoscale and Nanoscale Physics

12 pages, 10 figures

Scientific paper

10.5488/CMP.14.23705

Thermodynamics and kinetics of lithium intercalation into C--SiO$_2$ nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are explained based on the quantum effect of interference blockade of electron tunneling into a nonmetallic nanoparticle. Propositions for the new electrochemical energy storage technology are presented.

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