Physics – Condensed Matter – Statistical Mechanics
Scientific paper
1998-08-21
Physics
Condensed Matter
Statistical Mechanics
7 pages, no figures, IOP-style LaTeX, submitted to J. Phys. Condens. Matter (Letter to the Editor)
Scientific paper
10.1088/0953-8984/10/42/001
A method for calculating the short-range order part of the free energy of order-disorder systems is proposed. The method is based on the apllication of the cumulant expansion to the exact configurational entropy. Second-order correlation corrections to the mean-field approximation for the free energy are calculated for arbitrary thermodynamic phase and type of interactions. The resulting quadratic approximation for the correlation entropy leads to substantially better values of transition temperatures for the nearest-neighbour cubic Ising ferromagnets.
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