Pyroelectric vector and related polarization effects

Physics – Condensed Matter – Materials Science

Scientific paper

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4 pages, 1 figure, 1 table, RevTeX4. Submitted to Physical Review Letters

Scientific paper

The principal fact that the pyroelectric vector $\Pb^0$ typical of polar crystals is invisible in equilibrium has been verified. Nevertheless, the general formula for $\Pb^0$ as a definite bulk quantity associated only with the inversion properties of a given charge distribution in the bulk has been obtained. Its application to ferroelectric perovskites BaTiO$_3$, PbTiO$_3$, and KNbO$_3$ is discussed.

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