Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2009-04-07
Eur. Phys. J. E 29, 285-297 (2009)
Physics
Condensed Matter
Soft Condensed Matter
17 pages, 9 pictures
Scientific paper
10.1140/epje/i2009-10492-8
The thermally assisted detachment of a self-avoiding polymer chain from an adhesive surface by an external force applied to one of the chain ends is investigated. We perform our study in the "fixed height" statistical ensemble where one measures the fluctuating force, exerted by the chain on the last monomer when a chain end is kept fixed at height $h$ over the solid plane at different adsorption strength $\epsilon$. The phase diagram in the $h - \epsilon$ plane is calculated both analytically and by Monte Carlo simulations. We demonstrate that in the vicinity of the polymer desorption transition a number of properties like fluctuations and probability distribution of various quantities behave differently, if $h$ rather than $f$ is used as an independent control parameter.
Bhattacharya Sailajananda
Milchev Andrey
Rostiashvili Vakhtang G.
Vilgis Thomas A.
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