Physics – Condensed Matter – Materials Science
Scientific paper
2010-11-22
J. Am. Chem. Soc., 2010, 132 (50), pp 17664--17666
Physics
Condensed Matter
Materials Science
12 pages, 10 figures, accepted by JACS
Scientific paper
10.1021/ja107874u
A simple method for the preparation of PdCo@Pd core-shell nanoparticles supported on carbon has been developed using an adsorbate-induced surface segregation effect. The stability and electrocatalytic activity for the oxygen reduction of PdCo@Pd nanoparticles was enhanced by a small amount of Pt, deposited via a spontaneous displacement reaction. The facile method described herein is suitable for large-scale lower cost production and significantly lowers the Pt loading and thus cost. The as-prepared PdCo@Pd and Pd-decorated PdCo@Pd nanocatalysts have higher methanol-tolerance for the ORR when compared to Pt/C, and are promising cathode catalysts for fuel cell applications.
Abruna Héctor D.
Muller David A.
Rus Eric
Wang Deli
Wang Hongsen
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