Pressure-induced phonon frequency shifts in transition-metal nitrides

Details Pressure-induced phonon frequency shifts in transition-metal nitrides Pressure-induced phonon frequency shifts in transition-metal nitrides

2004-01-09

arxiv.org/abs/cond-mat/0401163v1

Physics

Condensed Matter

Superconductivity

19 pages and 6 figures

Scientific paper

10.1103/PhysRevB.70.014501

We report the first experiments on the high pressure phonon spectra of transition-metal nitrides HfN, ZrN, and NbN, obtained by Raman scattering measurements. Two pronounced bands, which are related to the acoustic part at low frequency around 200 cm$^{-1}$ and the optical part at high frequency around 550 cm$^{-1}$ of the phonon spectrum, respectively, shift to high frequency values with increasing pressure. An analysis of the results allows us to reproduce the experimental pressure dependence of the superconducting transition temperature $T_{c}$ of ZrN and NbN.

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