Physics – Condensed Matter – Superconductivity
Scientific paper
2008-02-22
Physics
Condensed Matter
Superconductivity
9 pages, 3 figures
Scientific paper
By means of synchrotron X-ray diffraction, we studied the effect of high pressure, P, up to 13 GPa on the room temperature crystal structure of superconducting CaC6. In this P range, no change of the pristine space group symmetry, \textit{R\=3m}, is found. However, at 9 GPa, i.e. close to the critical value at which a large T_c reduction was reported recently, we observed a compressibility jump concomitant to a large broadening of Bragg peaks. The reversibility of both effects upon depressurization and symmetry arguments give evidence of an order-disorder phase transition of second order, presumably associated with the Ca sublattice, which provides a full account for the above Tc reduction.
Bendiab Nedjma
Calandra Matteo
Canny B.
d'Astuto Matteo
Emery Nicolas
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