Power-law setting of steady concentration in a binary solution within a droplet at diffusion-controlled or free-molecular regimes of the droplet binary growth in the vapor-gas environment

Details Power-law setting of steady concentration in a binary solution within a droplet at diffusion-controlled or free-molecular regimes of the droplet binary growth in the vapor-gas environment Power-law setting of steady concentration in a binary solution within a droplet at diffusion-controlled or free-molecular regimes of the droplet binary growth in the vapor-gas environment

2009-01-22

arxiv.org/abs/0901.3423v1

Physics

Condensed Matter

Statistical Mechanics

Scientific paper

The times required for reaching the power-law-in-time growth of the droplet radius after nucleation of a markedly supercritical binary droplet, are found analytically and estimated at diffusion-controlled or free-molecular regimes of isothermal binary vapor condensation. The process of setting steady concentration in the binary solution within the growing droplet at the same regimes of binary condensation has been analyzed. It has been shown that setting the steady droplet concentration has also a power-law character in time. The parameters of the power law are specified for each regime of binary condensation and are linked to thermodynamic and kinetic characteristics of condensing vapors and to the steady concentration established in a binary droplet.

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