Polymer Brushes in Cylindrical Pores: Simulation versus Scaling Theory

Details Polymer Brushes in Cylindrical Pores: Simulation versus Scaling Theory Polymer Brushes in Cylindrical Pores: Simulation versus Scaling Theory

2006-03-18

arxiv.org/abs/cond-mat/0603474v2

Physics

Condensed Matter

Soft Condensed Matter

35 pages, 38 figures

Scientific paper

10.1063/1.2211615

The structure of flexible polymers endgrafted in cylindrical pores of
diameter D is studied as a function of chain length N and grafting density
\sigma, assuming good solvent conditions. A phenomenological scaling theory,
describing the variation of the linear dimensions of the chains with \sigma, is
developed and tested by Molecular Dynamics simulations of a bead-spring model.

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