Physics – Condensed Matter – Materials Science
Scientific paper
2000-09-14
Phys. Rev. Lett. 86, 3891 (2001)
Physics
Condensed Matter
Materials Science
REVTeX file. 4 pages. New version after referees' comments
Scientific paper
10.1103/PhysRevLett.86.3891
The origin of ultrahigh piezoelectricity in the relaxor ferroelectric PbZn1/3Nb2/3O3-PbTiO3 was studied with an electric field applied along the [001] direction. The zero-field rhombohedral R phase starts to follow the direct polarization path to tetragonal symmetry via an intermediate monoclinic M phase, but then jumps irreversibly to an alternate path involving a different type of monoclinic distortion. Details of the structure and domain configuration of this novel phase are described. This result suggests that there is a nearby R-M phase boundary as found in the Pb(Ti,Zr)O3 system.
Cox Dave E.
Cross L. E.
Noheda Beatriz
Park S-E.
Shirane Gen
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