Physics – Condensed Matter – Materials Science
Scientific paper
2004-11-05
Phys. Rev. B 71, 094112 (2005)
Physics
Condensed Matter
Materials Science
submitted to Phys. Rev. B, 9 pages, 10 figures
Scientific paper
10.1103/PhysRevB.71.094112
Dielectric, anelastic and ^139La NMR relaxation measurements have been made on the relaxor ferroelectric Pb(1-3x/2)La(x)Zr(0.2)Ti(0.8)O(3) (PLZT) with x = 0.22. The dielectric susceptibility exihibits the frequency dispersive maximum due to the freezing of the polar degrees of freedom around T ~250 K. The anelastic and especially NMR relaxation, besides this maximum, indicate an intense and broad component at lower temperatures, attributed to rotational modes of the O octahedra, weakly coupled to the polar modes. It is discussed why such short range rotational instabilities, known to occur in the Zr-rich rhombohedral region of the PLZT phase diagram, might appear also in the Ti-rich region.
Cordero Fernando Febres
Corti Mariela
Craciun F.
Galassi C.
Piazza Daniele
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