Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2010-04-09
Physics
Condensed Matter
Soft Condensed Matter
21 pages, 14 figures; Submitted to Journal of Rheology
Scientific paper
Dilute Laponite suspensions in water at low salt concentration form repulsive colloidal glasses which display physical aging. This phenomenon is still not completely understood and in particular, little is known about the connection between the flow history, as a determinant of the initial state of the system, and the subsequent aging dynamics. Using a stress controlled rheometer, we perform stress jump experiments to observe the elastic component of the flow stress that remains on cessation of flow or flow quenching. We investigate the connection between the dynamics of these residual stresses and the rate of physical aging upon quenching from different points on the steady state flow curve. Quenching from high rates produces a fluid state, G">G', with small, fast relaxing residual stresses and rapid, sigmoidal aging of the complex modulus. Conversely, quenching from lower shear rates produces increasingly jammed states featuring slowly relaxing stresses and a slow increase of the complex modulus with system age. Flow cessation from a fixed shear rate with varying quench durations shows that slower quenches produce smaller residual stresses at short times which relax at long times by smaller extents, by comparison with faster quenches. These smaller stresses are correlated with a higher modulus but slower physical aging of the system. The characteristic time for the residual stress relaxation scales inversely with the quench rate. This implies a frustrated approach to any ideal stress-free state that succinctly reflects the frustrated nature of these glassy systems.
Negi Ajay Singh
Osuji Chinedum O.
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