Photoluminescence from nanocrystalline graphite monofluoride

Details Photoluminescence from nanocrystalline graphite monofluoride Photoluminescence from nanocrystalline graphite monofluoride

2010-07-29

arxiv.org/abs/1007.5222v1

Applied Physics Letters, 97, 141915 (2010)

Physics

Condensed Matter

Materials Science

11 pages including supporting information, 2 figures

Scientific paper

10.1063/1.3491265

We synthesize and study the structural and optical properties of nanocrystalline graphene monofluoride and graphite monofluoride, which are carbon-based wide bandgap materials. Using laser excitations 2.41 - 5.08 eV, we identify six emission modes of graphite monofluoride, spanning the visible spectrum from red to violet. The energy and linewidth of the modes point to defect-induced midgap states as the source of the photoemission. We discuss possible candidates. Our findings open the window to electro-optical applications of graphene fluoride.

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