Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2002-10-09
Physics
Condensed Matter
Statistical Mechanics
Proceedings of the conference on Localization and Energy Transfer in Nonlinear Systems, June 17-21, 2002, San Lorenzo de El Es
Scientific paper
The basic models of helix-coil transitions in biomolecules are introduced. These include phenomenological, zipper (Bragg-Zimm) models of polypeptides, loop-entropy (Poland-Scheraga) and Hamiltonian (Peyrard-Bishop) models of homogeneous DNA denaturation. The transfer integral approach to one-dimensional thermodynamics is presented in some detail, including the necessary extensions to deal with the singular integral equations arising in the case of on-site potentials with a flat top. The (non-)applicability of the theorems which prohibit phase transitions in one-dimensional systems is discussed.
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