Phase separation in star polymer-colloid mixtures

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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4 pages, 4 figures, submitted to PRL

Scientific paper

10.1103/PhysRevE.64.010401

We examine the demixing transition in star polymer-colloid mixtures for star arm numbers f=2,6,16,32 and different star-colloid size ratios. Theoretically, we solve the thermodynamically self-consistent Rogers-Young integral equations for binary mixtures using three effective pair potentials obtained from direct molecular computer simulations. The numerical results show a spinodal instability. The demixing binodals are approximately calculated, and found to be consistent with experimental observations.

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