Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2000-10-12
Physical Review E 64, 010401(R) (2001)
Physics
Condensed Matter
Soft Condensed Matter
4 pages, 4 figures, submitted to PRL
Scientific paper
10.1103/PhysRevE.64.010401
We examine the demixing transition in star polymer-colloid mixtures for star arm numbers f=2,6,16,32 and different star-colloid size ratios. Theoretically, we solve the thermodynamically self-consistent Rogers-Young integral equations for binary mixtures using three effective pair potentials obtained from direct molecular computer simulations. The numerical results show a spinodal instability. The demixing binodals are approximately calculated, and found to be consistent with experimental observations.
Allgaier J.
Dzubiella Joachim
Ferber Christian von
Jusufi Arben
Likos Christos N.
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