Phase diagram of a solution undergoing inverse melting

Details Phase diagram of a solution undergoing inverse melting Phase diagram of a solution undergoing inverse melting

2008-02-27

arxiv.org/abs/0802.4046v1

Physics

Condensed Matter

Soft Condensed Matter

4 pages, 5 figures, accepted on Physical Review E (R)

Scientific paper

10.1103/PhysRevE.78.020502

The phase diagram of $\alpha$-cyclodextrin/water/4-methylpyridine solutions, a system undergoing inverse melting, has been studied by differential scanning calorimetry, rheological methods, and X-rays diffraction. Two different fluid phases separated by a solid region have been observed in the high $\alpha$-cyclodextrin concentration range ($c$$\geq$150 mg/ml). Decreasing $c$, the temperature interval where the solid phase exists decreases and eventually disappears, and a first order phase transition is observed between the two different fluid phases.

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