Phase diagram analysis and crystal growth of solid solutions Ca_{1-x}Sr_xF_2

Details Phase diagram analysis and crystal growth of solid solutions Ca_{1-x}Sr_xF_2 Phase diagram analysis and crystal growth of solid solutions Ca_{1-x}Sr_xF_2

2007-08-31

arxiv.org/abs/0708.4323v2

Journal of Crystal Growth 310 (2008)152-155

Physics

Condensed Matter

Materials Science

accepted for publication in J. Crystal Growth

Scientific paper

10.1016/j.jcrysgro.2007.09.031

The binary phase diagram CaF$_2$--SrF$_2$ was investigated by differential thermal analysis (DTA). Both substances exhibit unlimited mutual solubility with an azeotropic point showing a minimum melting temperature of T_\mathrm{min}=1373^{\circ}$C for the composition Ca$_{0.582}$Sr$_{0.418}$F$_2$. Close to this composition, homogeneous single crystals up to 30 mm diameter without remarkable segregation could be grown by the Czochralski method.

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