Physics – Condensed Matter – Materials Science
Scientific paper
2003-10-28
Physics
Condensed Matter
Materials Science
15 pages, 5 figures. Europhysics Letters (2003), in press
Scientific paper
10.1209/epl/i2003-00278-2
Ion conducting $(CaO)_x(SiO_2)_{1-x}$ glasses and melts show a threshold behaviour in dc conductivity near $x=x_t=0.50$, with conductivities increasing linearly at $x>x_t$. We show that the behaviour can be traced to a rigid ($x<0.50$) to floppy ($x>0.50$) elastic phase transition near $x=x_t$. In the floppy phase, conductivity enhancement is traced to increased mobility or diffusion of $Ca^{2+}$ carriers as the modified network elastically softens.
Chaimbault F.
Malki Mohammed
Micoulaut Matthieu
Simon Pascal
Vaills Y.
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