Peculiarities in the behavior of the entropy diameter for molecular liquids as the reflection of molecular rotations and the excluded volume effects

Details Peculiarities in the behavior of the entropy diameter for molecular liquids as the reflection of molecular rotations and the excluded volume effects Peculiarities in the behavior of the entropy diameter for molecular liquids as the reflection of molecular rotations and the excluded volume effects

2010-06-19

arxiv.org/abs/1006.3900v3

Physics

Condensed Matter

Statistical Mechanics

22 pages, 8 figures, 3 Tables

Scientific paper

10.1016/j.molliq.2011.03.016

The behavior of the diameter of the coexistence curve in terms of the entropy and the corresponding diameter are investigated. It is shown that the diameter of the coexistence curve in term of the entropy is sensitive to the change in the character of the rotational motion of the molecule in liquid phase which is governed by the short range correlations. The model of the compressible effective volume is proposed to describe the phase coexistence both in terms of the density and the entropy.

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