Partition functions and dissociation constants for zirconium oxide

Details Partition functions and dissociation constants for zirconium oxide Partition functions and dissociation constants for zirconium oxide

Nov 1983

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983apj...274..916s&link_type=abstract

Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 274, Nov. 15, 1983, p. 916-918.

Physics

Condensed Matter

Statistical Mechanics

3

S Stars, Stellar Atmospheres, Zirconium Oxides, Coefficients, Constants, Dissociation, Statistical Mechanics

Scientific paper

Internal partition functions and pressure dissociation constants are recomputed for ZrO for a temperature range from 1000 to 8000 C using the latest molecular constants available, including triplet splittings with appropriate weight factors. For low temperatures the resulting internal partition function values are about 20 percent lower than Tatum's (1966), while at higher temperatures the differences are as small as 5 percent. The large difference at low temperatures is caused by the choice of ground state level.

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