Partial decoupling between strain and polarization in mono-oriented Pb(Zr0.2Ti0.8)O3 thin film

Physics – Condensed Matter – Materials Science

Scientific paper

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11 pages, 3 figures

Scientific paper

10.1063/1.2742313

The structural evolution of epitaxial mono-oriented (i.e. with the c-axis perpendicular to the interface) ferroelectric Pb(Zr0.2,Ti0.8)O3 thin film has been investigated, using high resolution, temperature dependent, X-ray diffraction. The full set of lattice parameters was obtained, it allowed to estimate the variation of the polarization as a function of temperature, underlying the difference between the polarization-induced tetragonality and the elastic one. The temperature evolution of the misfit strain has been calculated and found to be in good agreement with the theoretical temperature-misfit strain phase diagram

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