Pair interactions between complex mesoscopic particles from Widom's particle-insertion method

Details Pair interactions between complex mesoscopic particles from Widom's particle-insertion method Pair interactions between complex mesoscopic particles from Widom's particle-insertion method

2010-10-07

arxiv.org/abs/1010.1422v1

Physics

Condensed Matter

Soft Condensed Matter

7 pages, 4 figures, to be published in Soft Matter

Scientific paper

10.1039/C0SM00815j

We demonstrate that Widom's particle insertion technique provides a convenient and efficient method to determine the effective pair interaction between complex, composite soft-matter particles in the zero-density limit. By means of three different test systems, i.e. amphiphilic dendrimers, electrostatic polymers and colloids coated with electrostatic polymers, we demonstrate the validity and the power of the presented method.

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