Overscreening in 1D lattice Coulomb gas model of ionic liquids

Details Overscreening in 1D lattice Coulomb gas model of ionic liquids Overscreening in 1D lattice Coulomb gas model of ionic liquids

2011-07-06

arxiv.org/abs/1107.1050v1

Physics

Condensed Matter

Statistical Mechanics

4 pages 5 .eps figures

Scientific paper

Overscreening in the charge distribution of ionic liquids at electrified interfaces is shown to proceed from purely electrostatic and steric interactions in an exactly soluble one dimensional lattice Coulomb gas model. Being not a mean-field effect, our results suggest that even in higher dimensional systems the overscreening could be accounted for by a more accurate treatment of the basic lattice Coulomb gas model, that goes beyond the mean field level of approximation, without any additional interactions.

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