Physics
Scientific paper
Jun 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..conferd05z&link_type=abstract
"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec
Physics
Mini-Symposium: Spectroscopic Perturbations
Scientific paper
The optical spectrum of chloro-methylene, HCCl, has been studied for more than 40 years by both conventional and laser-based spectroscopy. Surprisingly, numerous visible bands have yet to be characterized, due in part to known perturbations. Furthermore, the permanent electric dipole moment, μEl, for any state has yet to be determined. Here we report on the field-free and optical Stark spectrum of the tilde{A}1A'' (060)- tilde{X}1A '(000) band system. A cold molecular beam sample was produced by skimming the output of a pulsed discharge source and the spectrum recorded at a resolution of approximately 30 MHz via LIF detection. The field-free spectrum was analyzed to produce an improved set of spectroscopic parameters for the tilde{A}1A''(060)state. The Stark induced shifts were analyzed to determine the values of the a-component of μEl for the tilde{X}1A^ {'}(000)state of 0.498(8)D. Small perturbations in the tilde{A}1A''(060)state will be described.
A. J. Merer and D.N. Travis Can. J. Phys., 44, 525 1966.
M.Kakimoto, S.Saito and E. Hirota J.Mol.Spectrosc., 97, 194 1983.
B.-C.Chang and T. Sears J.Mol.Spectrosc., 173, 391 1995.
H. Fan, I. Ionescu, C. Annesley, J. Cummins, M. Bowers and S. A. Reid J.Mol.Spectrosc., 225, 43 2004.
Steimle Timothy C.
Wang Zhong
Zhuang Xiujuan
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