Optical Properties of MFe_4P_12 filled skutterudites

Details Optical Properties of MFe_4P_12 filled skutterudites Optical Properties of MFe_4P_12 filled skutterudites

1999-06-04

arxiv.org/abs/cond-mat/9906056v1

Phys.Rev.B, Vol.60, 11321 (1999)

Physics

Condensed Matter

Strongly Correlated Electrons

Manuscript in ReVTeX format, 7 figures in PostScirpt format

Scientific paper

10.1103/PhysRevB.60.11321

Infrared reflectance spectroscopy measurements were made on four members of the MFe_4P_12 family of filled skutterudites, with M=La, Th, Ce and U. In progressing from M=La to U the system undergoes a metal-insulator transition. It is shown that, although the filling atom induces such dramatic changes in the transport properties of the system, it has only a small effect on lattice dynamics. We discuss this property of the compounds in the context of their possible thermoelectric applications.

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