On resonant scatterers as a factor limiting carrier mobility in graphene

Physics – Condensed Matter – Mesoscale and Nanoscale Physics

Scientific paper

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version 2: several comments are taken into account and refs added

Scientific paper

10.1021/nl101399r

We show that graphene deposited on a substrate has a non-negligible density of atomic scale defects. This is evidenced by a previously unnoticed D peak in the Raman spectra with intensity of about 1% with respect to the G peak. We evaluated the effect of such impurities on electron transport by mimicking them with hydrogen adsorbates and measuring the induced changes in both mobility and Raman intensity. If the intervalley scatterers responsible for the D peak are monovalent, their concentration is sufficient to account for the limited mobilities achievable in graphene on a substrate.

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