Nonradiative Recombination of Excitons in Carbon Nanotubes Mediated by Free Charge Carriers

Physics – Condensed Matter – Mesoscale and Nanoscale Physics

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18 pages, 4 figures. Submitted to Physical Review B

Scientific paper

10.1103/PhysRevB.78.155429

Free electrons or holes can mediate the nonradiative recombination of excitons in carbon nanotubes. Kinematic constraints arising from the quasi one-dimensional nature of excitons and charge carriers lead to a thermal activation barrier for the process. However, a model calculation suggests that the rate for recombination mediated by a free electron is the same order of magnitude as that of two-exciton recombination. Small amounts of doping may contribute to the short exciton lifetimes and low quantum yields observed in carbon nanotubes.

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