Nonlinear Screening and Effective Interactions in Charged Colloids

Details Nonlinear Screening and Effective Interactions in Charged Colloids Nonlinear Screening and Effective Interactions in Charged Colloids

2001-10-04

arxiv.org/abs/cond-mat/0110096v2

Physics

Condensed Matter

Soft Condensed Matter

4 pages, 4 figures

Scientific paper

Influences of nonlinear screening on effective interactions between spherical macroions in charged colloids are described via response theory. Nonlinear screening, in addition to generating effective many-body interactions, is shown to entail essential corrections to the pair potential and one-body volume energy. Numerical results demonstrate that nonlinear effects can substantially modify effective interactions and thermodynamics of aqueous, low-salt suspensions of highly-charged macroions.

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