Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2011-01-20
Nature 467 (2010), 947-950
Physics
Condensed Matter
Soft Condensed Matter
15 pages, 4 figures
Scientific paper
10.1038/nature09427
Electrophoresis is a motion of charged dispersed particles relative to a fluid in a uniform electric field. The effect is widely used to separate macromolecules, to assemble colloidal structures, to transport particles in nano- and micro-fluidic devices and displays. Typically, the fluid is isotropic (for example, water) and the electrophoretic velocity is linearly proportional to the electric field. In linear electrophoresis, only a direct current (DC) field can drive the particles. An alternate current (AC) field is more desirable because it allows one to overcome problems such as electrolysis and absence of steady flows. Here we show that when the electrophoresis is performed in a nematic fluid, the effect becomes strongly non-linear with a velocity component that is quadratic in the applied voltage and has a direction that generally differs from the direction of linear velocity. The new phenomenon is caused by distortions of the LC orientation around the particle that break the fore-aft (or left-right) symmetry. The effect allows one to transport both charged and neutral particles, even when the particles themselves are perfectly symmetric (spherical), thus enabling new approaches in display technologies, colloidal assembly, separation, microfluidic and micromotor applications.
Lavrentovich Oleg D.
Lazo Israel
Pishnyak Oleg P.
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